The Sodium Silicate – Hydrogen Peroxide System
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The Oxidation of Sodium Lactate by Hydrogen Peroxide
By means of a modification of the technique of the Osterhout apparatus it is possible to follow the production of CO(2) from sodium lactate when acted upon by H(2)O(2). The results of this process indicate that the reaction is not a simple one but is of an autocatalytic type. This conclusion is borne out by the fact that the determinations of H(2)O(2) during the reaction show an increased amoun...
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The rate of decomposition of hydrogen peroxide has been measured in aqueous, concentrated (0.1–1M) reagent-grade sodium carbonate liquors and compared with that in sodium hydroxide liquors at the same pH, temperature, and ionic strength. Over the ranges of temperature (303–323 K), pH (10.0–10.6), and ionic strength (1.5–3.0M), and without peroxide-stabilizing additives, hydrogen peroxide decomp...
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The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free e...
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ژورنال
عنوان ژورنال: Nature
سال: 1960
ISSN: 0028-0836,1476-4687
DOI: 10.1038/185761a0